ASF

ASF is based on serialized objects which are essentially byte sequences identified by a GUID marker. The format does not specify how (i.e. with which codec) the video or audio should be encoded; it just specifies the structure of the video/audio stream. This is similar to the function performed by the QuickTime, AVI, or Ogg container formats. One of the objectives of ASF was to support playback from digital media servers, HTTP servers, and local storage devices such as hard disk drives.

- - Wikimedia

WMV

Windows Media Video (WMV) is a series of video codecs and their corresponding video coding formats developed by Microsoft. It is part of the Windows Media framework. WMV consists of three distinct codecs: The original video compression technology known as WMV, was originally designed for Internet streaming applications, as a competitor to RealVideo. The other compression technologies, WMV Screen and WMV Image, cater for specialized content.

- - Wikimedia

Step-By-Step to Convert ASF to WMV for Mac

Interface

Step 1. Download and install the program, then double click it to run it, and then you'll see the main interface of the program.

Load Files

Step 2. Click "Add File(s)" button. Here you can select "Add Video" or "Add Folder" button to add files as you like.

Profile

Step 3. Click the drop-down arrow right beside the "Profile" column and select your desired video format from the drop-down list.

Edit

Step 4. Click "Edit" button to customize the output video like Effect, Trim, Crop, 3D Settings and Watermark.

More Reading